CLBO Crystal – Cesium Lithium Borate Nonlinear Optical Crystal

  • Excellent UV Transmission down to 180 nm
  • High Nonlinear Coefficient for efficient frequency conversion
  • Wide Phase-Matching Range for SHG, THG, and OPO applications
  • High Laser Damage Threshold (> 2 GW/cm²)
  • Low Absorption in UV and Visible Range
  • Suitable for High-Average-Power Lasers
  • Large Aperture Crystal Growth up to 20 × 20 mm available
  • Ideal for Deep-UV Generation (<200 nm)

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Description

CLBO (Cesium Lithium Borate, CsLiB₆O₁₀) is a high-performance nonlinear optical (NLO) crystal widely used for deep UV and UV laser generation. With its high nonlinear coefficient, excellent UV transparency, wide phase-matching range, and high damage threshold, CLBO has become a preferred crystal for frequency conversion of Nd:YAG, excimer, and tunable lasers.

Compared with BBO and LBO, CLBO offers higher effective nonlinearities in the deep-UV region and outstanding performance for high-power continuous-wave (CW) applications, making it ideal for generating wavelengths below 200 nm.

Key Features and Properties

  • Excellent UV Transmission down to 180 nm
  • High Nonlinear Coefficient for efficient frequency conversion
  • Wide Phase-Matching Range for SHG, THG, and OPO applications
  • High Laser Damage Threshold (> 2 GW/cm²)
  • Low Absorption in UV and Visible Range
  • Suitable for High-Average-Power Lasers
  • Large Aperture Crystal Growth up to 20 × 20 mm available
  • Ideal for Deep-UV Generation (<200 nm)

Typical Applications

  • Deep-UV laser generation (DUV)
  • SHG/THG/FHG of Nd:YAG lasers
  • Generation of 193 nm, 213 nm, and <200 nm UV light
  • Optical Parametric Oscillators (OPOs)
  • Pump sources for photolithography
  • High-power industrial and medical UV laser systems
  • Laser spectroscopy and nonlinear optics research

Crystal Structure & Material Properties

  • Chemical Formula: CsLiB₆O₁₀
  • Crystal System: Tetragonal
  • Growth Method: Czochralski
  • UV Cutoff: ~180 nm
  • Transmission Range: 180–2800 nm
  • Excellent birefringence for phase matching
  • High structural stability at elevated laser power

Note: CLBO is slightly hygroscopic, so it requires careful handling and storage.

Standard Dimensions & Specifications

  • Aperture sizes: 3×3 mm², 4×4 mm², 5×5 mm², 10×10 mm² (custom sizes available)
  • Cutting angles for phase matching (θ, φ): according to application
  • Surface quality: 20/10 or 40/20 Scratch-Dig
  • Polish: λ/8–λ/10 at 632.8 nm
  • Parallelism: <20 arcsec
  • Perpendicularity: <15 arcmin
  • Coatings:
    • AR@355 nm
    • AR@266 nm
    • AR@193/213 nm (optional)

Technical Datasheet

Chemical Formula CsLiB₆O₁₀
Crystal Structure Tetragonal
Transmission Range 180 – 2800 nm
UV Cutoff ~180 nm
Refractive Indices nx = 1.61, ny = 1.56, nz = 1.55 (typical)
Effective Nonlinear Coefficient d_eff ≈ 0.7 pm/V
Phase-Matching Type Type I & Type II
Density 2.62 g/cm³
Mohs Hardness ~5
Melting Point ~1100 °C
Hygroscopicity Slightly hygroscopic
LDT (CW) > 500 MW/cm²
LDT (Nanosecond) > 2 GW/cm²
Thermal Expansion α ≈ 6.5 ×10⁻⁶ /K
Standard Surface Quality 20/10 or 40/20
Orientation Tolerance <0.1°
Coating Options AR@355 nm, AR@266 nm, AR@193 nm

 

Customization Options

  • Custom phase-matching angles for SHG/THG/FHG
  • High-damage-threshold AR coatings
  • High-power grade with reduced internal absorption
  • Special length and aperture sizes for deep-UV setups
  • Crystal mounting and dry-pack service to prevent moisture absorption

Packaging and Delivery

  • Vacuum-sealed moisture-proof packaging
  • Dry nitrogen storage for CLBO crystals
  • Cleanroom-safe hard case protection
  • Expedited delivery for standard sizes
  • Custom orders shipped based on fabrication schedule

Why Choose Our CLBO Crystals

  • High-purity raw materials ensuring low absorption
  • Precision phase-matching and strict quality control
  • Superior polishing and coating for UV laser applications
  • Flexible customization and competitive pricing
  • Experienced supplier for global laser & photonics companies

Ordering & Contact Information

We offer flexible MOQ (Minimum Order Quantity), competitive pricing and global shipping. For custom orders or technical inquiries, please contact us for a detailed consultation!